(343f) Dynamic Operation of Batch Reverse Osmosis and Batch Pressure Retarded Osmosis

Optimal control theory is applied to dynamic operation of batch reverse osmosis (RO) for seawater desalination and batch pressure retarded osmosis (PRO) for power generation. It is proved that the water flux should be constant during the entire operation in order to minimize specific energy consumption (SEC) in RO or to maximize specific energy production (SEP) in PRO. A dimensionless parameter γ = A_m L_pÏ€₀t_f/V₀, similar to the one used in continuous osmotic membrane processes, is proposed to characterize the energy performance. While the SEC in RO is a monotonic function of recovery and γ, the SEP in PRO is solely a monotonic function of γ. It is shown that batch RO/PRO excels continuous RO/PRO because it mitigates the spatial variation of flux in a long pressure vessel observed in the latter. The batch operation provides an elegant way to implement continuous multi-stage RO with interstage pumps and an energy recovery device (ERD) as well as continuous multi-stage PRO with interstage turbines. Some tradeoff between energy efficiency and flux is deemed necessary. A preliminary cyclic diagram to operate the batch PRO is proposed.

References:

[1] Li, M. Dynamic Operation of Batch Reverse Osmosis and Batch Pressure Retarded Osmosis, Industrial & Engineering Chemistry Research, 59, 3097-3108, 2020.

[2] Li, M. Systematic Analysis and Optimization of Power Generation in Pressure Retarded Osmosis: Effect of Multi-Stage Design, AIChE Journal, 64, 144-152, 2018.

[3] Li, M. Reducing Specific Energy Consumption in Reverse Osmosis (RO) Water Desalination: An Analysis from First Principles, Desalination, 276, 128-135, 2011.