(64c) Dynamic Glass Based on Reversible Metal Electrodeposition

Glass that electronically tints allows users to optimize for human comfort and energy efficiency amid dynamic environments and dispositions. Traditional electrochromic materials, which change color in electric fields, are implemented or considered in an array of applications, but widespread market adoption is inhibited by persistent challenges with color, cost, speed, and durability. We have developed a distinct approach to dynamic glass that utilizes reversible electroplating of metals. Metals are an attractive class of materials for dynamic glass due to their strong interaction with light, photochemical inertness, and compatibility with environmentally benign solvents like water. By tuning the morphology and composition of metallic films, we have control over properties like absorption, reflection, and color. Our metal-based dynamic windows exhibit true color neutrality, superior energy performance, and can tint to a privacy state with < 0.1 % transmission.

Metal-based dynamic glass operates on the electrochemical phase change between metal cations dissolved in an electrolyte and elemental metal plated on a transparent conducting electrode. The thickness, morphology, and composition of the plated metal film dictates the optical properties of the dynamic glass. To enable uniform plating of metal over large areas, transparent electrodes are coated with a monolayer of Pt nanoparticles. The nanoparticles act as seeds that control where the metal nucleates and how it grows on the electrode. We use an aqueous, nonhalide-based electrolyte with enhanced durability that permits reversible metal electrodeposition without harming the electrode or introducing irreversible side reactions that inhibit cycle life. With this electrolyte, we demonstrate 10,000 stable cycles with color-neutral, fast switching (<1 minute), high optical contrast (>60%), and extended shelf life (>8 months). We also demonstrate how polymeric additives in the electrolyte influence the growth

of the metallic films and thus enable direct control over the unique optical properties of our devices. Finally, we present large-area prototypes (15cm x 15cm) with uniform tinting and discuss our path towards full-scale (> 1 m²) dynamic windows. We are optimistic that windows based on reversible metal electrodeposition will be cheaper than ones based on sputtering of metal oxides since the electrolyte is inexpensive and can be injected into the window using low cost methods.

We will discuss the advantrages and disadvantages of counter electrodes based on visible metal grids, invisible metal micromeshes and metal oxides.

Fig.1 Photographs of RME dynamically tinted windows under optical switching.

References

[1] C. J. Barile, M. D. McGehee, et. al, Joule, 1, 133 (2017).

[2] T. S. Hernandez, M. D. McGehee, et. al, ACS Energy Letters, 3, 104 (2018).

[3] M. T. Strand, M. D. McGehee, et. al, ACS Energy Letters, 3, 11 (2018).