(662a) Metal-Oxide Nanoarray based Catalysts for Water Electrolysis and CO2 conversion at High Efficiency and Low Cost | AIChE

(662a) Metal-Oxide Nanoarray based Catalysts for Water Electrolysis and CO2 conversion at High Efficiency and Low Cost

Authors 

Gao, P. X. - Presenter, University of Connecticut
Three-dimensional (3-D) assemblies of nanomaterials into applicable platforms or devices demand to meet the practical requirements in cost-effectiveness, structure sophistication, multi-function enabling, green and robust operations. Such integration process and product enabling involve dissimilar nano-building-blocks such as particles, wires, and films made of metals, ceramics, or polymers. In this talk, I will review our decade-long research effort in the assemblies and integrations of various ceramics and metals in the forms of nanostructure arrays (nanoarrays) onto different macroscale surfaces as function-carrying reactors and devices. Departing from automotive catalytic converters, sensors, water electrolysis, to CO2-methanol conversion, a unique green process and product engineering pathway is being laid out with nanomaterial design, function-enabling, manufacturing capability, system integratability, and economic affordability as the underlying bases. Modular, multifunctional, and scalable nanoarray devices and systems are being designed and enabled for conversion, monitoring, production, and redistribution of fuels and chemicals such as carbon dioxide, hydrogen, and methanol.

References:

  1. Zhang, J.Y. Sun, U. Salahudin, P.X. Gao, “Hierarchical and Scalable Integration of Nanostructures for Energy and Environmental Applications: A Review of Processing, Devices, and Economic Analyses,” Nano Futures, 2020, 4, 012002.
  2. B. Wang, Z. Ren, Y.B. Guo, P.X. Gao, “Nano-array integrated monolithic devices: toward rational materials design and functional performance by scalable self-assembly of nanostructures”, CrystEngComm 2016, 18, 2980 - 2993.
  3. Hoang, and P.X. Gao, “Nanowire Array Structures for Photocatalytic Energy Conversion and Utilization: A Review of Design concepts, Assembly and Integration, and Function Enabling,” Adv. Energy Mater. 2016, 6, 1600683.
  4. Hoang, Y. Guo, A.J. Binder, W. Tang, S. Wang, H. Tran, J.J. Liu, X. Lu, Y. Wang, Y. Ding, E.V. Kyriakidou, J. Yang, T.J. Toops, T.R. Pauly, R. Ramprasad, and P.X. Gao, “Activating Low-temperature Diesel Oxidation by Single-Atom Pt on TiO2 Nanowire Array” Nature Communications, 2020, 11, 1062.
  5. Y. Wen, R. Xu, C. Cui, W. Tang, Y. Mi, X.X. Lu, Z. Zeng, S.L. Suib, P.X. Gao, and Y. Lei, “Template-guided programmable Janus hetero-nanostructure arrays for efficient plasmonic photocatalysis” Nano Letters, 2018, 18(8), 4914-4921.
  6. S. Du, W. Tang, X. Lu, S. Wang, Y. Guo, P.X. Gao, “Cu-supported ZnO Nanoarray Integrated Structured Catalysts for Low-pressure CO2 Hydrogenation to Methanol,” Adv. Mater. Int. 2018, 5, 1700730.