(313d) Pfas Fate and Transport Study in Contaminated Sediments Utilizing Capping Methods and Sorbent Amendments

Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) are two important organic chemicals of the per- and polyfuoroalkyl substances (PFAS) group that have contaminated land, water, and the air since 1950. The continuous release of PFAS from the surface of land into water is not easy to forecast and an appropriate treatment method needs to be economically viable since there are currently around 42,000 suspect industrial and municipal sites in the United States. For a true reproduction of real-world pollution patterns, we constructed polypropylene tanks, performed laboratory-based experiments, and analyzed the samples using EPA method 537. In this study, we examined the fate and transportation of long- and short-chain PFAS, including PFOA, PFOS, and perfluorobutanesulfonic acid (PFBS), from sediments, adsorbent media, and sands under overlaying water tanks. Activated carbon (GAC), biochar (BC), and fluorosorb (FS) were also added between the contaminated sediments and the sand layer in order to observe capping effectiveness. As one of the best ways to treat contaminated sediments on a large scale, adsorbent beds may reduce contaminants migration and support the degradation of contaminants. We found that all three chemicals were able to pass through the adsorbent layers of 3-4 inches from 4-5 inches of contaminated sediments and reach the top surface of the beds (25-30 inches). In the top 5-7 inches, PFBS concentration varies from 0.28 ppb to 0.78 ppb for all adsorbent tanks for 7 days. Whereas the bottom contaminated sediments concentrations of PFBS were 8517.6 ppb to 9480.7 ppb. We also observed the concentrations at top ports increased by 0.59 ppb to 2.31 ppb in 21 days, and ultimately, 0.58 ppb to 7.07 ppb in 69 days. While PFOA and PFOS found different metabolites in all layers, they provided noticeably lesser concentrations in contaminated sediments compared to PFBS. Further, the results of this study can be useful for validating the contaminant transport model predictions by identifying linear or nonlinear sorption equilibrium processes and diffusion-dispersion processes in sediment, sand, and various adsorbent media.