(536n) Refractory Tungsten ALD Coatings for Nuclear Thermal Propulsion Fuel Elements
AIChE Annual Meeting
2022
2022 Annual Meeting
Particle Technology Forum
Poster Session: Particle Technology Forum
Wednesday, November 16, 2022 - 3:30pm to 5:00pm
In this work, we utilize particle atomic layer deposition (ALD) to synthesize a tungsten coating on yttria-stabilized zirconia (YSZ) ceramic particles as a surrogate for UO2. Particle ALD is performed by sequentially dosing WF6 and Si2H6 into a fluidized bed of YSZ powder, which deposits a tungsten metal coating by self-limited surface reactions to create a nearly conformal 350 nm coating (Figure 1). Thermal treatments are used to evaluate the stability of the coated powders in a dilute hydrogen environment up to 1773 K. Further characterization of the powder by SEM-EDS after high-temperature hydrogen exposure is used to elucidate microstructural changes to the coating and fuel surrogate. To evaluate the ALD tungsten coating under more realistic NTP conditions, a test matrix is developed to compare the performance of the W-coated YSZ particles to the uncoated baseline YSZ particles in a variety of refractory metal matrices using spark-plasma sintering for consolidation. The consolidated cermet samples are then treated with pure hydrogen at >2000 K in MSFCâs CFEET facility to simulate conditions approximating NTP engine operation. Microstructural analysis with SEM and XRD, as well as characterization of surrogate fuel mass loss is used to evaluate the effectiveness of the ALD tungsten coating in preventing cermet degradation. This is the first instance of an ALD coating being incorporated into an NTP cermet via SPS, as well as the first test of such a coating under realistic operating conditions. This research advances our understanding of how refractory metal ALD coatings behave under high-temperature and introduces a new technique to improve the durability of NTP engines for deep-space exploration.