(180e) Ni-Co Nanorods Decorated on Mo-Assisted NiS2 Nanoflowers Heterostructured Fully Fledged on Ni-Form for Fostering the Performance of Asymmetric Supercapisitors
AIChE Annual Meeting
2024
2024 AIChE Annual Meeting
Materials Engineering and Sciences Division
Poster Session: Materials Engineering & Sciences (08E - Electronic and Photonic Materials)
Monday, October 28, 2024 - 3:30pm to 5:00pm
The fabricating composite electrodes have succeeded in boosting their energy storage. This involves creating an interface through rational construction that may include doping or integration with their components. In this study, Mo-doped nickel sulfide nanoflowers (MNS) coupled with Ni-Co nanorods (NiCo) constructed directly on Ni foam (MNS@NiCo NSs) were elatedly designed via facile hydrothermal technique. This tech has limited the resistance and maximized the sample utilization. The entwined nanorods were spread over the interconnected nanoflowers; this coupling-designed nanostructure could supply a plentiful active network to accelerate the electrolyte penetrations with many redox-active sites during the electrochemical process. The MNS@NiCo NSs designed mesoporous nanostructures and improved wettability by providing higher capacitances of 455 C/g at 1 A/g. After being integrated with NiCo-nanoflowers, the MNS@NiCo NSs composite delivered higher capacitances of 505 C/g at 1 A/g. Also, the made asymmetric supercapacitor (MNS@NiCo NSs//AC) achieved higher energy densities of 38.1 W h/kg at power densities of 775 W/kg, delivering superior cycling stability even over 5000 long cycles with a capacitance retention of 92% at 10 A/g current density. The noteworthy energy capability of MNS@NiCo NSs occurs from the synergistic benefactions of MNS nanoflowers and Ni-Co nanorods. Such high performance is due to engineering in the synthesis of such potential heterostructures.