(179c) Molecular Anchor Pt Nanoparticles on Multi-Walled Carbon Nanotubes as Fuel Cell Electrocatalysts | AIChE

(179c) Molecular Anchor Pt Nanoparticles on Multi-Walled Carbon Nanotubes as Fuel Cell Electrocatalysts

Authors 

Chen, Z. - Presenter, University of California, Riverside
Deng, W. - Presenter, California Institute of Technology
Wang, X. - Presenter, Department of Chemical and Environmental Engineering, University of California, Riverside
Goddard, W. A. III - Presenter, California Institute of Technology
Yan, Y. - Presenter, University of Delaware


Molecular anchor will dramatically improve the electrocatalytic activity of electrocatalysts. Our previous calculation results show that the molecular anchor can improve internal conductivity ~100 times larger than van der waals connection, which enhance the electron transport process in electrochemical process. Here different surface functionalized (-NH2, -COOH, -SH, purified) multi-walled carbon nanotubes supported Pt nanocatalysts (2-5 nm) were prepared by ethylene glycol (EG) method. The catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and cyclic voltammetry (CV) as well as linear voltammetry. The Electrocatalytic activity of these nanocatalysts are in the order of -NH2 > -COOH > purified > -SH. Polarization and power density data in a proton exchange membrane fuel cell (PEMFC) test were in good agreement with the electrochemical characterization and calculation results.