(457e) Dependence of S-I Thermochemical Decomposition Process Configuration and Efficiency on Property Models
AIChE Annual Meeting
2007
2007 Annual Meeting
Nuclear Energy and the Hydrogen Economy
Benchmarking of Thermochemical Cycles for Advanced Hydrogen Manufacturing Processes
Wednesday, November 7, 2007 - 4:55pm to 5:15pm
Using both a model-free analysis described previouslya,b, and Aspen Plus flowsheeting, several property model methods have been applied to obtain and compare the effects on the energy and entropy flows for selected S-I processes, including fully integrated plants. It has been found that, although the differences in properties among the modeling approaches appear to be small, their use leads to significant changes in overall efficiency and irreversibility estimates; stream flows; process unit configuration; and even flowsheet convergence. In addition, a survey of the literature shows that different workers do not use the same input and output conditions. These variations suggest that appropriate comparisons among different programs can be problematic.
The presentation will show examples of the analyses and raise questions about how to standardize process formulation and results to provide maximum communication effectiveness and reliable foundations for selecting among, and improving, proposed alternative processes.
a AIChE Annual Meeting, Cincinnati, OH, November 2005
b AIChE Annual Meeting, San Francisco, CA, November 2006
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