(179v) Water Droplet On Self-Assembled Fluorocarbon Surface: Hydrophobic-Induced Surface Reorganization
AIChE Annual Meeting
2009
2009 Annual Meeting
Engineering Sciences and Fundamentals
Poster Session: Interfacial Phenomena
Monday, November 9, 2009 - 6:00pm to 8:00pm
We carried out molecular dynamics simulations of water droplets on self-assembled monolayers of perfluorocarbon molecules. The interactions between the water droplet and the hydrophobic fluorocarbon surface were studied by systematically changing the molecular surface coverage and the mobility of the tethered head groups of the surface chain molecules. The microscopic contact angles were determined for different fluorocarbon surface densities. The contact angle at a nanometer length scale showed no apparent trend with the surface density. The behavior of water density profile near a hydrophobic surface was closely examined in terms of monolayer structure and water penetration. At surface densities near close packed coverage of fluorocarbons, the water density formed an oscillating pattern near the boundary with a robust layered structure. As the surface density decreased and more water molecules penetrated into the fluorocarbon surface, the ordering of the water molecules at the boundary became less apparent and the layered density structure became diffuse. The water droplet is found to induce the interfacial surface molecules to rearrange and form unique topological structures that minimize the unfavorable water-surface contacts. The local density of the fluorocarbon molecules right below the water droplet is measured to be higher than the density outside the droplet. The density difference increases as the overall surface density decreases. Two different surface morphologies emerged from the water-induced surface reorganization over the range of surface coverage explored in the study. For surface densities near closed packed monolayer coverage, the height of the surface is maximum at the center of the droplet and minimum at the water-vapor-surface triple junction, generating a convex surface morphology under the droplet. For lower surface densities, on the other hand, the surface height becomes maximum at and right outside the water-vapor-surface triple junction and decreases quickly towards the center of the droplet, forming a concave shape of the surface. The spontaneous surface organization in response to the water molecules is found to have profound consequences in many aspects of surface-water interactions, including water depletion and penetration, hydrogen bonding, and surface morphologies.