(420a) Solution Spinning of Neat Carbon Nanotube Fiber, Effect of Carbon Nanotube Length and Processing | AIChE

(420a) Solution Spinning of Neat Carbon Nanotube Fiber, Effect of Carbon Nanotube Length and Processing

Authors 

Pasquali, M. - Presenter, Rice University
Behabtu, N. - Presenter, Rice University
Young, C. C. - Presenter, Rice University
Tsentalovich, D. - Presenter, Rice University
Ma, A. - Presenter, Rice University
Matteni, F. - Presenter, Rice University
Bengio, A. - Presenter, Rice University
Talmon, Y. - Presenter, Technion-Israel Institute of Technology
Kleinerman, O. - Presenter, Technion-Israel Institute of Technology
Schmidt, J. - Presenter, Technion-Israel Institute of Technology
Kesselman, E. - Presenter, Technion-Israel Institute of Technology
Cohen, Y. - Presenter, Technion-Israel Institute of Technology
Otto, M. - Presenter, Teijin Aramid BV
Hoogerwerf, R. - Presenter, Teijin Aramid BV
Waarbeek, R. - Presenter, Teijin Aramid BV
deJong, J. - Presenter, Teijin Aramid BV


Transferring the exceptional single molecule properties of carbon nanotubes (CNTs) into macroscopic articles such as fibers and films has been a major challenge in the past two decades.  Two approaches have merged. The first is solid state processing, where fibers and films are directly spun from the synthesis reactor or nanotube forest. The second is wet spinning, where carbon nanotubes are first dissolved and spun in fibers or cast into films.

Here we show recent progress on super-acid solution spinning. Nanotube length and quality have a significant effect on processability, mechanical and electrical properties. We also show the impact of processing variables on fiber alignment and properties and demonstrate process scalability by demonstrating high throughput spinning, which is orders-of-magnitude higher than solid state processing.

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