(564e) Production of Synthetic Paraffin Kerosene by Hydrocracking Fischer-Tropsch Wax

The US Air Force has committed to an
alternative aviation-fuel initiative to implement a roadmap for testing and
certifying alternative fuel components including biomass-derived alternatives
produced from non-food plants, animal fats, and algae, as well as synthetic
fuel components derived from domestic coal and natural gas.  The initiative
includes the certification of fuel blends for the entire fleet of USAF aircraft
as well as ground support equipment and vehicles. The Impact of these new fuel
blends on performance, the environment, safety and occupational health, and the
fuel storage and supply infrastructure are being examined.

In order to qualify fuel
components, the AF requires amounts ranging from initial samples of 20-30 mL to
larger scale quantities in the hundreds to thousands of gallons for test
operations both in the laboratory and in engines and aircraft. 

The characteristics of petroleum-based jet fuels as well as
coal and natural gas based synthetic jet fuels are well known. They contain
hydrocarbon compounds that form a bell-shaped distribution that ranges from a
carbon number of 8 to 16. In contrast, the fuel properties of biobased
components are less well defined, and depending on the generation process, may contain
narrower carbon-number distributions. A way to generate such specialized fuel
surrogates is needed to determine the effect of these new fuel components on
combustion efficiency, emissions, and fit-for-purpose performance.  To generate
these surrogates, the Air Force has erected a Sample Preparation Unit (SPU) at the
Assured Aerospace Fuels Research Facility (AAFRF) located at Wright-Patterson
Air Force Base.

The AAFRF Sample Preparation Unit includes the following sections:

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 Feed system

o  
 Pump to feed the liquid hydrocarbons

o  
 Booster compressor to feed hydrogen

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 Reaction

o  
 Mixer to blend fresh and recycled hydrocarbons with hydrogen
ahead of the reactors

o  
 High-pressure, high-temperature packed-bed reactors to convert
the feed

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 Distillation columns for product recovery

o  
 Fractionator (lighter component removal)

o  
 Vacuum column (synthetic paraffinic kerosene recovery; recycle
incompletely converted materials to the reactors)

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 Recycle compressor to reuse unreacted hydrogen. 

For acceptance tests the SPU was configured to hydrocrack
Fischer-Tropsch wax into synthetic paraffinic kerosene. The SPU was operated 24/7
at a production rate of approximately 10 gallons of synthetic jet fuel
materials per day.  The fuel surrogate produced met all the specifications of SPK
aviation turbine fuel (MIL-DTL-83133G) except conductivity (which could be met
through use of an additive).

This paper will describe the AAFRF
Sample Preparation Unit design, operational testing results, and future fuel-surrogate
production plans.