(371f) A Technique for Mass Balance of Process Data Using Linear Combination of LSQ and Lrsq | AIChE

(371f) A Technique for Mass Balance of Process Data Using Linear Combination of LSQ and Lrsq

Authors 

Salama, A. I. A. - Presenter, Natural Resources Canada


A TECHNIQUE FOR MASS BALANCE OF PROCESS DATA USING LINEAR
COMBINATION OF LSQ AND LRSQ

A. I. A.
Salama and T. Dabros

CanmetENERGY-Devon

Natural Resources Canada

Suite A202, #1 Oil Patch Drive, Devon, Alberta, Canada T9G 1A8

Phone (780) 987-8635, Fax
(780) 987-8676

E-mail:
Ahmed.Salama@NRCan-RNCan.gc.ca

 

Abstract

A technique is introduced for
mass balance of raw data of a flume process (used to simulate depositions of
solids on the beach of oil sands tailing ponds). The proposed objective
function of the optimization problem is a linear combination of the absolute
and the relative error squares.  In the conventional least-error-squares (LSQ) case,
the stream component (SC) errors are scaled by the standard deviations of the
raw SC data errors, however, in the least-relative-error-squares (LRSQ) case; the
errors are referenced to the raw SC values.  In the LRSQ case zero stream-components
in the raw data remain zeros in the optimal estimates which is not a feature in
the LSQ case.  Such advantage is important in applications where some SCs are
single component (i.e., water, steam, hydrocarbon solvent).

 

Keywords: Least-error-squares (LSQ) technique, Least-relative-error-squares
(LRSQ) technique, Mass balance technique, Flume test.

 
Demonstration

      Let us consider a two-dimensional case. The raw SCs are p1
and p2 and the corresponding estimates are x1 and x2
as shown in Fig 3.  The constraint, x1+x2=1 is imposed
and labeled the ?Solution line (SL)? (see Fig
3).  In the LSQ case the objective function is defined as f=(x1-p1)2+(x2-p2)2
The LSQ case solutions are concentric circles around the raw data point (p1,
p2).  The optimal solution is located when a concentric circle
becomes tangent to the SL and the solution is labeled XE*.  Close
observation of the LSQ solution indicates that: a) for all raw points on the
lines parallel above and below the SL generates the same adjustments and b) either
one of the SCs p1 or p2 becomes greater than one the
optimal solutions have negative values.  Both results are disadvantages.  The
LRSQ solution is the directed line from the raw data point (p1, p2)
to the SL and is labeled XR* (see Fig 3).  The XR*
solution indicates that: a) the corrections between XR* and P are
proportional to the ratio of p1 and p2 squared, and b) if
one of SCs, p1 or p2 ,becomes zero the
corresponding optimal SCs, x1* or x2*, are also zero.  In
this case both results are advantageous.  It should be emphasized that Fig 3 is
only given as demonstration but no further conclusions can be drawn.

A raw data set collected around the
CanmetENERGY-Devon flume unit is used to demonstrate the results.  The proposed
technique is implemented in spread sheet format using Microsoft Excel TM.

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