(234a) Fluorescence Properties of CMC/Eu Nanocomposites in Different Phs

CMC/Eu nanocomposites
were synthesized successfully by reacting with Eu³⁺ and CMC(70°æ,
15min) in waterbath. The FTIR results indicated the reaction between carboxyl
groups in CMC and Eu³⁺, and SEM results showed that the particles of
CMC/Eu nanocomposites were sphere and particle sizes were around 100 nm. In
addition, effect of pHs on the fluorescence properties of CMC/Eu
nanocomposites was complicated (see Figure). The emission spectra had red
shifts with increasing pH. The fluorescence intensities of the materials in
lower pHs were significantly stronger than that of materials in higher pH. It
might result from the degradation of ligand CMC in strong alkaline condition.

Acknowledgement:
Supported by the National 973
project under Grant No. 2010CB732201, the National Natural Foundation of China
under Grant No 31270617 and the Opening Project of State Key Laboratory of
Polymer Materials Engineering (Sichuan University) under Grant No. KF201301.

Figure. Emission spectra of CMC/Eu
nanocomposites synthesized in different pHs.