(395t) Microwave Synthesis and Characterization of MOF-74 (M = Ni, Mg) for Gas Separation

Isostructural MOF-74 (M = Ni, Mg) were successfully synthesized with both hydrothermal method (1 and 3) and microwave-assisted method (2 and 4). These MOF-74 samples were characterized with scanning electron microscopy for crystal structure, powder X-ray diffraction for phase structure, and nitrogen adsorption for pore textural properties. The experimental results showed that MOF-74 samples synthesized by the microwave-assisted method have a smaller particle size with relatively more uniform particle size distribution. The microwave effects also helped to produce a larger specific surface area and micropore volume, with a similar median pore diameter. Adsorption equilibrium and kinetics of various gases (CO₂, CH₄, N₂, C₂H₄, C₂H₆, C₃H₆ and C₃H₈) on these MOF-74 samples were determined at 298 K and gas pressures up to 1 bar. Adsorption equilibrium selectivity (α), combined equilibrium and kinetic selectivity (β), and adsorbent selection parameter for pressure swing adsorption processes (S) were estimated. The relatively high values of adsorption selectivity indicates the potential to separate CO₂/CH₄, CO₂/N₂, C₂H₄/C₂H₆, C₃H₆/C₃H₈ and C₃H₆/C₂H₄ pairs in a vacuum swing adsorption process using the MOF-74 adsorbent. The microwave-assisted method was found to improve MOF-74 with a larger adsorption capacity and higher selectivity for gas separation.