(449c) Low Temperature Non-Catalytic Transfer Hydrogenation of Coal in Supercritical CO2

The
paper describes the findings from experimental investigations related to the development  and
characterization of a low temperature (<150 ^oC)
non-catalytic process using a hydrogen transfer agent (instead of molecular hydrogen)
for coal dissolution in supercritical CO₂.  The key idea is that one hydrogen atom from
water (W) and one hydrogen atom from the hydrogen transfer agent (HTA) will be
used to hydrogenate the coal.  Since the products of coal dissolution are
expected to be non-polar and polar while the supercritical CO₂,
which is expected to promote disruption the coal structure, enhance the rates
of hydrogenation and dissolve the non-polar molecules and remove them from the
reaction site, is non polar, a polar modifier (PM)
modifier for CO₂ is added to aid in the dissolution and removal of
the polar components.  In addition, to allow a seamless transport of the
ions (HTA) and byproduct (reduced HTA) between the aqueous and organic phases,
a phase transfer agent (PTA), is added.  

COAL
+ HTA +H₂O → COAL.H₂ + reducedHTA

The attractive feature of this process is that the liquid
chemicals are obtained without requiring to first convert
coal to CO and H₂ units. The results show that the process can
extract chemicals from coal at temperatures ranging between 80 - 140 ^oC.  The results also show that straight
chain hydrocarbons for transportation fuels as well as chemicals such as
aromatics with one two or three benzene rings that are needed as chemical
precursors for commercial organics, can be extracted from coal by this
process.  The amount of liquid produced was found to be enhanced if a coal
structure disruption step is carried out before the coal hydrogenation
step.  This can be achieved by the sudden expansion of the supercritical
CO₂.  Incidentally the use of supercritical CO₂ not
only provides high dissolution strength but also allows for easy separation of
the chemicals from the solvent (normally gaseous under room conditions). 
The effect of the mixture composition of coal/W/HTA/PM/PTA as well as the
effect of temperature and pressure will be presented.  It should be noted that this process can be
used for the extraction of chemicals from biomass, presumably even from lignocellulosic materials.