(561e) Giant Magnetoresistacne in Conducting Polymers and Their Nanocomposites
AIChE Annual Meeting
2013
2013 AIChE Annual Meeting
Materials Engineering and Sciences Division
Organic and Hybrid Semiconductors
Wednesday, November 6, 2013 - 4:45pm to 5:03pm
In this talk, the fundamentals of giant magnetoresistance (GMR) in the conducting polymers and their nanocomposites are presented. Both positive and negative GMR can be obtained in the conducting polymers and their nanocomposites for the highly disorderedly localized system in the Mott variable range hopping regime. The obtained positive GMR in the silica/polyaniline nanocomposites is analyzed by the wave-function shrinkage model and negative GMR is interpreted by the forward interference model. The results have found that the GMR is related to the changed localization length (a0), density of states at the Fermi level (N(EF)), and average hopping length Rhop. An observed transition from positive to negative GMR in the silicon/polyaniline nanocomposites is around magnetic field of 5.5 T. The theoretical analysis reveals that both the wave-function shrinkage model and the forward interference model contribute to the positive GMR and only forward interference model is responsible for the observed negative GMR.