(15b) Catalytic Dehydration of Methyl Lactate
AIChE Annual Meeting
2014
2014 AIChE Annual Meeting
Catalysis and Reaction Engineering Division
In Situ and Operando Spectroscopy of Catalysts
Sunday, November 16, 2014 - 3:50pm to 4:10pm
Catalytic dehydration of methyl lactate to acrylic acid and methyl acrylate on NaY is investigated via in-situ transmission FTIR spectroscopy. Ion exchange, Bronsted acid site-mediated dehydration and displacement reaction are proposed to be the key mechanistic steps in the surface mediated chemical transformation. Design principles for bifunctional catalysts have been developed based on the mechanistic insights will be discussed.