(415b) Persistently Auxetic Materials (PAMs): Engineering the Poisson Ratio of 2D Self-Avoiding Membranes with Finite Anisotropic Strain

Entropic surfaces such as fluctuating 2D membranes are predicted to have desirable mechanical properties when unstressed, including a negative Poisson’s ratio.  We present measurements of the strain-dependent Poisson ratio of self-avoiding membranes.  We show that finite size membranes with free boundary conditions in fact have a positive Poisson ratio due to spontaneous non-zero mean curvature, which can be suppressed with an explicit bending rigidity in agreement with literature.  Applying longitudinal strain to this system suppresses this mean curvature and entropic out-of-plane fluctuations, resulting in a negative Poisson’s above a critical strain, with Poisson ratios significantly more negative than the zero-strain limit for infinite sheets.  We find that this auxetic behavior persists to surprisingly high strains (over 20% for the smallest surfaces), and finite size effects are actually desirable in producing a surface with a negative Poisson ratio over a wide range of strains.  These results give clues to designing surfaces with a tunable negative Poisson ratio by using materials with a set amount of initial applied strain or adjusting the surface rigidity.