(202b) Tuning the Physicochemical Properties of Biochar Derived from Ashe Juniper By Vacuum Pressure and Temperature

Ashe juniper is a problematic plant in central Texas due to rapid expansion causing the alteration of rangeland plant communities and hydrological landscapes. The thermochemical conversion of Ashe juniper into biochar with specific properties is a promising way for valorization of Ashe juniper. This study presents the effects of temperature (350, 450 and 520°C) and vacuum pressure (0.09, 0.7 and 3 kPa) on physical and chemical properties of biochar produced by vacuum pyrolysis from Ashe juniper. We found that temperature had a major effect on the degree of carbonization, surface functionality, as well as the O/C and H/C ratios regardless of vacuum pressure. The severity of vacuum pressure effects on product properties was found to depend on pyrolysis temperature. It was also confirmed that the vacuum pressure was a crucial factor for controlling the surface area and porosity at each constant pyrolysis temperature. This work also demonstrated that the biochar from Ashe juniper under vacuum pyrolysis showed improved aromaticity and surface area over the reported biochar derived from other raw biomass. Biochar produced at 450 and 520°C showed potential application as an adsorbent, a catalyst support and a carbon sequestration agent. Methylene blue (MB) adsorption test confirmed that biochar produced at 450°C and 0.7 kPa showed potential as an adsorbent.