(375b) Electric Current-Induced Nanoscale Surface Roughness Reduction in Conducting Thin Films
AIChE Annual Meeting
2017
2017 Annual Meeting
Materials Engineering and Sciences Division
Nanoelectronic and Photonic Materials I: Nanoscale Applications
Tuesday, October 31, 2017 - 12:41pm to 12:52pm
Toward this end, in this presentation, we report a modeling and simulation study that has established the electrical surface treatment of conducting thin films as a viable physical processing strategy for surface roughness reduction. We have developed a continuum model of surface morphological evolution that accounts for the residual stress in the deposited conductor film, surface diffusional anisotropy and film texture, the filmâs wetting of the layer that is deposited on, and surface electromigration. Supported by linear stability theory, self-consistent dynamical simulations based on the model demonstrate that the action over several hours of a sufficiently strong and properly directed electric field on a conducting thin film can reduce its nanoscale surface roughness and lead to a smooth planar film surface. The modeling predictions are in good agreement with experimental measurements on copper thin films deposited on silicon nitride layers. Moreover, through systematic linear stability analyses and dynamic simulation protocols, we have examined in detail the effects of film texture and applied electric field direction and optimized the electrical surface treatment by minimizing the electric current density required for film surface smoothening. We have found that the critical electric field strength requirement for surface roughness reduction on {110}, {100}, and {111} copper film surfaces exhibits a very strong dependence on the applied electric field direction, i.e., the electric field alignment with respect to the principal residual stress directions in the film and the fast surface diffusion direction.