(690e) Hydrogen Fueled Micro-Fuel Cell with Microfluidic Channels on a PFSA Plane
AIChE Annual Meeting
2017
2017 Annual Meeting
Fuels and Petrochemicals Division
Unconventionals: Hydrogen and Fuel Cells
Thursday, November 2, 2017 - 9:40am to 10:05am
Many efforts on fuel cell miniaturization are focused on silicon-based techniques as silicon is the most common substrate in MEMS technology [6, 7]. However, combining silicon devices with polymeric fuel cells at mm or sub-mm scale presents many challenges, none of which have been solved in a completely satisfactory manner [8]. Furthermore, in recent years due to material property issues associated with PDMS such as bulk absorption of small molecules and evaporation through the device, there has been a tendency towards the employment of thermoplastics for microfluidic systems [9].
Distinct from previous attempts on fabricating in-plane μFCs in other studies, in this work we present a novel On-Membrane Micro Fuel Cell design where the micro-flow channels for fuel and oxidant input are fabricated by using a combination of laser micromachining and hot-bonding process. In preparation of the device, a laser patterned acrylic sheet was pressed onto the Nafion substrate by a gas-cushion hot-bonding and the inlet tubes were mounted on the acrylic sheet. The micro device performance was characterized by I-V polarization curves and impedance spectroscopy under dry and humidified conditions. The combined in-plane and through-plane flux of protons in the membrane can be compared to literature data.
With this fabrication technology high aspect ratio structures can be fabricated over large surface areas, which prompts a commercially successful manufacturing of polymer-based micro-components.
Refrences:
1. Sundarrajan, S., Allakhverdiev, S. I., & Ramakrishna, S. (2012). Progress and perspectives in micro direct methanol fuel cell. International Journal of Hydrogen Energy, 37(10), 8765-8786.
2. Taylor, A. D., Lucas, B. D., Guo, L. J., & Thompson, L. T. (2007). Nanoimprinted electrodes for micro-fuel cell applications. Journal of Power Sources, 171(1), 218-223.
3. Z. Yuan, J. Yang, Y. Zhang and X. Zhang, "The optimization of air-breathing micro direct methanol fuel cell using response surface method," Energy, vol. 80, pp. 340-349, 2015.
4. Kamarudin, S. K., Daud, W. R. W., Ho, S. L., & Hasran, U. A. (2007). Overview on the challenges and developments of micro-direct methanol fuel cells (DMFC).Journal of Power Sources, 163(2), 743-754.
5. Cao, J., Xu, J., Chen, Z., Wang, W., Huang, Q., & Zou, Z. (2013). A Silicon-based micro direct methanol fuel cell stack with a serial flow path design.International Journal of Energy Research, 37(4), 370-376.
6. Shah, K., Shin, W. C., & Besser, R. S. (2004). A PDMS micro proton exchange membrane fuel cell by conventional and non-conventional microfabrication techniques. Sensors and Actuators B: Chemical, 97(2), 157-167.
7. Lu, G. Q., Wang, C. Y., Yen, T. J., & Zhang, X. (2004). Development and characterization of a silicon-based micro direct methanol fuel cell.Electrochimica Acta, 49(5), 821-828.
8. Omosebi, A., & Besser, R. S. (2013). Fabrication and performance evaluation of an in membrane micro-fuel cell. Journal of Power Sources, 242, 672-676.
9. Sackmann, Eric K., Anna L. Fulton, and David J. Beebe. "The present and future role of microfluidics in biomedical research." Nature 507.7491 (2014): 181-189.