(276g) Strain Fields in Repulsive Colloidal Crystals
AIChE Annual Meeting
2018
2018 AIChE Annual Meeting
Engineering Sciences and Fundamentals
Directed and Self Assembly of Colloids
Tuesday, October 30, 2018 - 9:30am to 9:45am
Crystalline defects can be approximated as linear combinations of local motifs (strains) under the framework of linear elasticity theory. This approach has been widely employed in the metallurgical community; here we show that the elastic strain field approximation is a useful tool in colloidal crystalline systems as well.
This work explores the behavior of elastic moduli and strain fields around dislocations within simulated colloidal crystals interacting through a family of repulsive potentials with varying steepness. For steeper potentials, it is found that free energies of deformation are more dominated by entropy, tension-compression asymmetry near dislocation core increases, and the strain range of linear elastic applicability shrinks. We show that pressure is a key parameter for expanding the window of linear elastic applicability for very steep potentials. Using these insights, we show under what conditions linear elasticity theory can be used as a predicative tool in exploring defect-defect interactions in colloidal crystals.