(399d) Electro-Oxidation of Furans to Value-Added Chemicals
AIChE Annual Meeting
2018
2018 AIChE Annual Meeting
Catalysis and Reaction Engineering Division
Electrocatalysis and Photoelectrocatalysis VI: Biomass Processing and Ammonia Synthesis
Tuesday, October 30, 2018 - 4:24pm to 4:42pm
This study focuses on characterizing the partial electro-oxidation of furfural and HMF under acidic conditions on various noble metal catalysts. These biomass-derived model compoundsare derived from the acid-catalyzed conversion of lignocellulosic feedstocks and can yield value-added products such as furoic acid, maleic acid, and furan-dicarboxylic acid. A differential âflow-throughâ electrochemical reactor was paired with membrane-inlet mass spectrometry (MIMS) and LC-MS. We analyze the partial electro-oxidation of furans under a variety of conditions and discuss trends in product distributions as they pertain to possible reaction pathways. Ongoing work involves investigation of the reaction mechanisms through isotopic labeling experiments and electrochemical ATR-FTIR.