(544bm) Metal Supported Ultrathin Oxide/Oxyhydroxide Thin Films for Oxygen Reduction Reaction

A successful commercialization of fuel cell is currently limited by a lack of cost-effective and highly active electrocatalysts for a cathode reaction (oxygen reduction reaction, ORR). As a promising catalyst candidate for electrochemical reactions, partially oxidized ultrathin metal film supported on transition metal substrates have been investigated recently. Previous theoretical results by Greeley et al.¹ showed that partially oxidized metals can be stabilized by the presence of metal substrates, altering the stability of metal (hydroxyl-)oxide compared to the bulk counterparts. They also applied metal-supported thin films toward alkaline hydrogen evolution reaction, and calculations demonstrated its high potential to lower the reaction kinetic barriers.

In this talk, I will discuss the stability of various thin film metal (hydroxy-) oxides on various metal substrates. Cost-effective metal (hydroxy-) oxides on three face centered cubic (fcc) metal supports were considered. The density functional theory results show that most of metal (hydroxy-) oxide thin films are stabilized on metal supports, implying a possibility of metal-supported thin films to survive in ORR conditions. I will also discuss the applicability of these materials as ORR catalysts.

¹Z. Zeng, K. Chang, J. Kubal, N. Markovic and J. Greeley, Nature Energy 2, Article number: 17070 (2017)