(623a) Synergies between Heterogeneous Nanoparticles and Surfactants to Stabilize Emulsions
AIChE Annual Meeting
2019
2019 AIChE Annual Meeting
Engineering Sciences and Fundamentals
Anisotropic Particles: Synthesis, Characterization, Modeling, Assembly, and Applications
Thursday, November 14, 2019 - 8:00am to 8:15am
In this study, we investigate the stability of emulsions through dissipative particle dynamics (DPD) computations. An oil-water model is constructed based on the approach reported in previous studies [3, 4]. First, the change of oil-water IFT with the presence of surfactants and s[herical nanoparticles is studied. We have found that while NPs alone do not affect the IFT, they further reduce the IFT when surfactants are also present [5]. Then, the stability of emulsions with different emulsifiers is examined by allowing two oil-in-water droplets to collide. The stability is quantified as the force needed to break the droplets. It is shown that the presence of spherical NPs increases the emulsion stability in comparison to the case where there are only surfactants. Among different types of NPs, the Janus particles, which possess both hydrophobic and hydrophilic properties in two opposite sides show the highest effect in preserving the emulsions. This observation could be explained by the strong tendency to settle on the oil-water interface of Janus particles. The results provide details of the mechanism for the co-effect of NPs and surfactants in stabilizing emulsions.
ACKNOWLEDGEMENTS
The use of computing facilities at the University of Oklahoma Supercomputing Center for Education and Research (OSCER) and at XSEDE (under allocation CTS-090025) is gratefully acknowledged. Acknowledgment is made to the donors of The American Chemical Society Petroleum Research Fund for partial support of this research through grant PRF # 58518-ND9.
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