(86c) Development of Novel Reducing Agents for NOx Reduction by Sncr Method
AIChE Spring Meeting and Global Congress on Process Safety
2013
2013 Spring Meeting & 9th Global Congress on Process Safety
Environmental Division
Advanced Technologies for Reduction of Atmospheric Emissions in the Petrochemical and Refining Industries
Tuesday, April 30, 2013 - 3:30pm to 4:00pm
Nitric oxides (NOx), mainly including nitric oxide (NO) and nitrogen dioxide (NO2), are of the most toxic pollutants formed during combustion and refining processes. Post-combustion treatment methods include selective catalytic reduction (SCR), selective noncatalytic reduction (SNCR), reburning, and the combination of these aftertreatment technologies. Among the post-combustion technologies, the SNCR technology is considered to be an effective approach to reduce NOx, with reasonable capital investment and operation cost. To reduce NOx in a lean environment, a reductant is needed. For SNCR, the most commonly used reductant is ammonia or urea water solution as an alternative to NH3. One of the disadvantages of ammonia is the cost of the injection system. Different reducing agents for NOx removal by SNCR method will be evaluated in this paper, including carbon monoxide, hydrogen, char, hydrocarbons, and oxygenates, etc.