(48r) Characterization of Iron Phthalocyanine As the Active Material for Lithium Batteries

Results on the determination of the lithium-ion diffusion coefficient in the iron phthalocyanine (FePc) active material as a function of intercalation level, using a modified electrochemical impedance spectroscopy technique, will be presented.  Also, developed thermodynamic functions such as the Gibbs free energy, entropy, and enthalpy changes for the lithium insertion reaction with FePc, derived from cell open-circuit voltage measurements as a function of intercalation level, are presented.  Also presented are estimates of the maximum amount of lithium that can be intercalated into the FePc based on constant volume and temperature conditions.