Early Research Proves Synthesizing Polyester from CO2 is Possible | AIChE

Early Research Proves Synthesizing Polyester from CO2 is Possible

May
2023

Excess carbon dioxide can be transformed into polyester in a new method that uses electrolysis and microbial fermentation.

The process is carried out in two steps: First, the electrochemical conversion of gaseous carbon dioxide to formate, and then, in a separate reactor, the use of formate to “feed” the bacterium Cupriavidus necator, which produces the biodegradable, biocompatible polyester poly-3-hydroxybutyrate (PHB).

“Over the last ten years, a lot of people have jumped into this area of studying how to convert CO2 into some value-added product. However, previously, people studied methods where CO2 is bubbled through liquid water,” says Hyunjoo Lee, a chemical engineer at the Korea Advanced Institute of Science and Technology (KAIST). However, because the solubility of dissolved CO2 in water is so low and raising the pressure in a CO2 electrolyzer to increase the solubility is very difficult, the amount of product generated by this process would be too low for industrial-scale applications.

Decarbonization efforts, as well as the increased prevalence of carbon capture and storage (CCS), are making the use of CO2 for chemical production a more attractive endeavor. Lee and her...

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