Microwave Catalysis for Process Intensified Modular Production of Value-Added Chemicals from Natural Gas

The rise in US natural gas supplied, tied to challenges/costs associated with natural gas logistics, point to the value of converting natural gas to liquid products. Indirect routes are generally energy inefficient and capital intensive. In contrast, direct non-oxidative natural gas conversion eliminates the syngas production step and required oxygen generation. However, these technologies have not been commercialized because of technical challenges such as low selectivity, coking, heat management, catalyst deactivation and catalyst regeneration.

Investigators

John Hu
Professor, Engineering

Focus Areas

Date approved

November 01, 2017
Current TRL
5

Energy Efficient Separations of Olefins and Paraffins through a membrane

Throughout the petrochemical and refining industry, the separation of olefins and paraffins is generally performed via distillation, a costly and capital intensive method, particularly for light olefins. This project uses a silver-incorporated custom amorphous fluoropolymer membrane to separate olefins and paraffins. Compared to previous attempts using facilitated transport membranes, this membrane has been shown to have very good longevity in laboratory settings and has been tested with reasonably-expected process poisons.

Investigators

Hannah Murnen
Chief Technology Officer

Date approved

November 01, 2017
Current TRL
4

Modular Conversion of Stranded Ethane to Liquid Fuels

Ethane can represent up to 20 vol.% of shale-gas, exceeding the 10 vol. % allowed in “pipeline-quality” natural gas. Each year, over 210 million barrels (liquid equivalent) of ethane are rejected in the lower 48 states. Upgrading low- to negative-value ethane to easily transportable liquid fuels is a promising solution to this supply glut. The key to this process is development of modular systems that can operate economically at stranded sites. Conventional gas-to-liquids (GTL) technologies face significant challenges such as high capital cost and limited efficiency.

Investigators

Fanxing Li
Associate Professor

Date approved

January 01, 2018
Current TRL
4

Advanced Nanocomposite Membrane for Natural Gas Purification

Processing natural gas is the largest industrial application of gas separation membranes. Membranes occupy 10% of the ~$5 billion worldwide annual market for new natural gas separation equipment, with amine absorption accounting for most of the rest. While widely used, amine systems suffer from corrosion, complex process design, and equipment often unsuitable for offshore gas processing platforms. Amine systems are also less efficient than membranes at high CO2 concentrations.

Investigators

Benny Freeman
William J. (Bill) Murray, Jr. Endowed Chair of Engineering

Partner Organizations

University of Texas at Austin

Focus Areas

Date approved

November 01, 2017
Current TRL
4

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